Synthesis of ethyl propionate catalyzed by poly(N‐AEAAm‐co‐AAc)‐cl‐MBAm hydrogel‐immobilized lipase of Bacillus coagulans MTCC‐6375

A purified alkaline thermotolerant bacterial lipase of Bacillus coagulans MTCC‐6375 was efficiently immobilized onto poly(N‐AEAAm‐co‐AAc‐cl‐MBAm)‐hydrogel at pH 8.5 and at temperature 55°C in 16 h. The hydrogel‐bound matrix possessed 1.04 U/g (matrix) lipase activity with a specific activity of 1.8 U/mg of protein. The immobilized lipase resulted in formation of 52.5 mM of ethyl propionate (52% conversion) at 55°C in 9 h in n‐nonane. Ethanol and propionic acid when used in a ratio of 300 : 100 mM, respectively, in n‐nonane along with 10 mg of hydrogel‐bound lipase resulted in optimal synthesis of ethyl propionate (82.5 mM). Addition of molecular sieves (3 Å, 0.7 g/reaction volume) further enhanced the conversion rate to 82.4% resulting in 83.5 mM of ethyl propionate. Incubation temperature below or above 55°C had a marked effect on the synthesis of ethyl propionate. However, esterification performed in n‐heptane at 65°C resulted in 87.5 mM of ethyl propionate with a conversation rate of 89.3%. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Recycling of silicone rubber waste: Effect of ground silicone rubber vulcanizate powder on the properties of silicone rubber

The silicone rubber vulcanizate powder (SVP) obtained from silicone rubber by mechanical grinding exists in a highly aggregated state. The particle size distribution of SVP is broad, ranging from 2 µm to 110 µm with an average particle size of 33 µm. X‐ray Photoelectron Spectroscopy (XPS) and Infrared (IR) Spectroscopy studies show that there is no chemical change on the rubber surface following mechanical grinding of the heat‐aged (200°C/10 days) silicone rubber vulcanizate. Addition of SVP in silicone rubber increases the Mooney viscosity, Mooney scorch time, shear viscosity and activation energy for viscous flow. Measurement of curing characteristics reveals that incorporation of SVP into the virgin silicone rubber causes an increase in minimum torque, but marginal decrease in maximum torque and rate constant of curing. However, the activation energy of curing shows an increasing trend with increasing loading of SVP. Expectedly, incorporation of SVP does not alter the glass‐rubber transition and cold crystallization temperatures of silicone rubber, as observed in the dynamic mechanical spectra. It is further observed that on incorporation of even a high loading of SVP (i.e., 60 phr), the tensile and tear strength of the silicone rubber are decreased by only about 20%, and modulus dropped by 15%, while the hardness, tension set and hysteresis loss undergo marginal changes and compression stress‐relaxation is not significantly changed. Atomic Force Microscopy studies reveal that incorporation of SVP into silicone rubber does not cause significant changes in the surface morphology.     

Development of halogen‐free flame‐retardant thermoplastic elastomer polymer blend

Ethylene‐propylene diene rubber (EPDM) and isotactic polypropylene (iPP) blends have widest industrial applications that require a degree of flame retardancy. Halogen‐free intumescent technology based on phosphorous salt is a significantly advanced approach to make the polymer flame‐retardant. Both ammonium polyphosphate and ethylenediamine phosphate are important intumescent compounds. Their combination with carbonific and spumific agents were studied in binary blends of EPDM/PP. The polymer system was vulcanized online during melt mixing. Intumescent flame‐retardant polymer systems exhibit good flame‐retardancy with optimum comparable physiomechanical, electrical, and fluid resistance properties, including lower smoke emission, which is essential to protect people because the visibility remains unaffected in the event of fire. Pronounced charring and intumescent effect appear to enhance the flame‐retardancy of the polymers. Possible expected intumescent mechanism is proposed based on the nonpyrolysis mechanism for the flame‐retarded polymer and the intumescent components. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 407–415, 2004     

Numerical simulation and experimental investigation of gas–powder flow from radially symmetrical nozzles in laser-based direct metal deposition

Laser-based direct metal deposition (DMD) is a solid freeform fabrication process capable of fabricating fully dense and metallurgically sound parts. The process has been greatly enhanced toward multi-directional deposition by the use of discontinuous radially symmetrical powder nozzles to supply the build material. Since many operational parameters depend on the gas–powder stream characteristics between the nozzles and the deposition point, an extensive understanding of the gas–powder flow is necessary. Three-dimensional (3D) multi-phase gas–powder flow structures of radially symmetrical nozzles are modeled using computational fluid dynamics methods. The obtained results are in good agreement with the experimental ones, and they provide a good insight into the process phenomena.     

Response of Multilayer Foundation System beneath Railway Track under Cyclic Loading

For an efficient and economical design of a railway track system, it is necessary to understand the behavior of each track component with special reference to ballast and subgrade, which play a pivotal role in distributing the large, cyclic wheel loads longitudinally, laterally, and vertically away from the wheel contact area on the rail surface to the underlying soil strata. This paper presents an analytical model of a track-ballast-subgrade system with different formation soils such as dense uniform sand, stiff clay, loose sand, and soft clay modeled by using a mass-spring dashpot system with two degrees of freedom. This represents the varying energy distribution through ballast and subgrade in the vertical direction. Results are presented in the form of time-displacement response profiles for both the ballast and subgrade layers. In addition, the magnification factors for displacements with variation in subgrade soils for cyclic loading frequencies are reported. It is observed that the results obtained from the present analysis follow the experimentally observed trends already available in the literature.     

Structural Performance of Hybrid GFRP/Steel Concrete Sandwich Panels

Precast/prestressed concrete sandwich panels consist of two concrete wythes separated by a rigid insulation foam layer and are generally used as walls or slabs in thermal insulation applications. Commonly used connectors between the two wythes, such as steel trusses or concrete stems, penetrate the insulation layer causing a thermal bridge effect, which reduces thermal efficiency. Glass fiber-reinforced polymer (GFRP) composite shell connectors between the two concrete wythes are used in this research as horizontal shear transfer reinforcement. The design criterion is to establish composite action, in which both wythes resist flexural loads as one unit, while maintaining insulation across the two concrete wythes of the panel. The experiments carried out in this research show that hybrid GFRP/steel reinforced sandwich panels can withstand out-of-plane loads while providing resistance to horizontal shear between the two concrete wythes. An analytical method is developed for modeling the horizontal shear transfer enhancement using a shear flow approach. In addition, a truss model is built, which predicts the panel deflections observed in the experiments with reasonable accuracy.     

Posttraumatic distress and physical functioning: A longitudinal study of injured survivors of community violence.

This study examines the cross-lagged relationships between posttraumatic distress symptoms and physical functioning, using a sample of 413 persons who were hospitalized for injuries resulting from community violence. Posttraumatic distress was assessed at 1 week, 3 months, and 12 months postinjury, and posttraumatic physical functioning was assessed at 3 months and 12 months. Structural equation modeling was used to assess the prospective relationship between posttraumatic distress symptoms and physical functioning while controlling for demographic characteristics and objective measures of injury severity. Results indicate that posttraumatic distress and physical functioning are reciprocally related. Individuals with high levels of psychological distress at 1 week posttrauma have worse physical functioning at 3 months. Psychological distress at 3 months was not significantly associated with subsequent change in physical functioning at 12 months. Individuals with poor physical functioning at 3 months had higher than expected levels of psychological distress at 12 months. These findings demonstrate a reciprocal relationship between physical and mental health following traumatic injury. Interventions targeting physical recovery may influence subsequent mental health, and therapies aimed at improving early mental health may also have long-term benefits for physical recovery. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Numerical and experimental study of bistable piezoelectric energy harvester

Piezoelectric energy harvesting from mechanical vibrations is a reliable technology to charge low power electronic equipment. It has been reported in the literature that low frequency broadband vibrations cannot be harvested effectively using linear piezoelectric energy harvester (PEH). In this paper a bistable nonlinear PEH with two distinct energy wells generated using repulsive magnetic interactions between a cantilever magnetic proof mass and an external magnet is considered. It has been modeled using finite element method and validated with experimental results. Experimental results verify that, for our study, distance between magnetic proof mass and external magnet of 1.32 T flux density should be less than or equal to 8.5?mm for maintaining bistability. This distance also affects to the resonance frequency of harvester. Maximum efficiency of the harvester has been noticed at 8.5mm. Further it has been shown experimentally that the bistable nonlinear piezoelectric energy harvester takes almost half of the time taken by its linear counterpart to charge a 20 mAh battery.     

Electromagnetic radiation detection in 0-3 cement-PZT composite under impact loading

Electromagnetic responses of cement–PZT composites under impact loading have been presented in this work. The values of density, dielectric constant and EMR voltage increase while that of porosity and loss tangent decrease with increase in PZT content. Filler (PZT) concentration dependent dielectric constant as well as loss tangent data shows exponential variation. The emitted EMR voltage as well as average EMR energy release rate for 21?cm height of impact increase from 1.03 V to 2.24 V and 0.10092 V²-sec/sec to 0.4635 V²-sec/sec respectively with the increasing PZT content (5% to 40%). The EMR responses of the composites were also found to be proportional to the height of impact in all the composites tested, indicating that the measurement of EMR responses from the cement based composites may be useful for deformation monitoring.     

Generation of square and triangular wave with independently controllable frequency and amplitude using OTAs only and its application in PWM

This paper presents a self-generating square/triangular wave generator using only the CMOS Operational Transconductance Amplifiers (OTAs) and a grounded capacitor. The output frequency and amplitude of the proposed circuit can be independently and electronically adjusted. The proposed circuit validates its advantage by consuming less amount of power, which is about 71.3 µW. The theoretical aspects are authentically showcased using the PSPICE simulation results. The performance of the proposed circuit is also verified through pre layout and post layout simulation results using the 90 nm GPDK CMOS parameters. A prototype of this circuit has been made using commercially available IC CA3080 for experimental verification. Experimentation also gives the similar output as per the theoretical proposition. The designed circuit is also made applicable to perform pulse width modulation (PWM).